\(n_{Fe}=\dfrac{6,5}{56}=\dfrac{13}{112}mol\)

\(m_{CH_3COOH}=\dfrac{90\cdot20\%}{100\%}=18g\Rightarrow n_{CH_3COOH}=0,3mol\)

\(Fe+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Fe+H_2\uparrow\)

\(\dfrac{13}{112}\)       0,3                       0                        0

\(\dfrac{13}{112}\)       \(\dfrac{13}{56}\)                       \(\dfrac{13}{112}\)                   \(\dfrac{13}{112}\)

   0       \(\dfrac{19}{280}\)                      \(\dfrac{13}{112}\)                  \(\dfrac{13}{112}\)

a)\(m_{\left(CH_3COO\right)_2Fe}=\dfrac{13}{112}\cdot174=20,2g\)

\(m_{H_2}=\dfrac{13}{112}\cdot2=\dfrac{13}{56}g\)

\(m_{dd\left(CH_3COO\right)_2Fe}=6,5+90-\dfrac{13}{56}=96,27g\)

\(C\%=\dfrac{20,2}{96,27}\cdot100\%=20,98\%\)

2Na+2H2O→2NaOH+H2↑

0,2→ 0,2 0,1 mol

a.m ct NaOH=0,2 x40=8 g

C%A=C%NaOH= x100=8%

2NaOH+CuSO4→Na2SO4+Cu(OH)2↓

0,03 → 0,03 0,03 mol

mdd sauC=30+50-0,03 x98=77,06 g

mct Na2SO4=0,03 x142=4,26 g

C%Na2SO4= x100≈5,53 %

b.Cu(OH)2to→CuO+H2O

CuO+ H2→ Cu↓+ H2O

0,0325 ←0,0325

m X=m CuO=0,0325 x80=2,6 g

*tk(hoidap)

a) PTHH: \(FeCl_3+3NaOH\rightarrow3NaCl+Fe\left(OH\right)_3\downarrow\)

                 \(2Fe\left(OH\right)_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+6H_2O\)

b) Ta có: \(n_{FeCl_3}=0,3\cdot0,5=0,15\left(mol\right)\)

\(\Rightarrow n_{NaOH}=0,45mol\) \(\Rightarrow V_{ddNaOH}=\dfrac{0,45}{0,25}=1,8\left(l\right)\)

c) Theo PTHH: \(n_{NaCl}=n_{NaOH}=0,45mol\)

\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,45}{2,1}\approx0,21\left(M\right)\) 

(Coi như thể tích dd thay đổi không đáng kể)

d) Theo PTHH: \(n_{H_2SO_4}=\dfrac{3}{2}n_{Fe\left(OH\right)_3}=\dfrac{3}{2}n_{FeCl_3}=0,225mol\)

\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,225\cdot98}{20\%}=110,25\left(g\right)\) 

\(\Rightarrow V_{ddH_2SO_4}=\dfrac{110,25}{1,14}\approx96,71\left(ml\right)\)

a. PTHH: \(CuSO_4+2NaOH--->Na_2SO_4+Cu\left(OH\right)_2\downarrow\)

b. Đổi 100ml = 0,1 lít

Ta có: \(n_{Cu\left(OH\right)_2}=\dfrac{9,8}{98}=0,1\left(mol\right)\)

Theo PT: \(n_{CuSO_4}=n_{Cu\left(OH\right)_2}=0,1\left(mol\right)\)

=> \(m_{CuSO_4}=0,1.160=16\left(g\right)\)

c. Theo PT: \(n_{NaOH}=2.n_{CuSO_4}=2.0,1=0,2\left(mol\right)\)

=> \(C_{M_{NaOH}}=\dfrac{0,2}{0,1}=2M\)

Gọi \(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\n_{Al}=y\left(mol\right)\end{matrix}\right.\)

\(n_{BaSO_4}=\dfrac{11,65}{233}=0,05\left(mol\right)\)

\(Mg+CuSO_4\rightarrow MgSO_4+Cu\)

x------>x--------->x------------>x

\(2Al+3CuSO_4\rightarrow Al_2\left(SO_4\right)_3+3Cu\)

y------>1,5y-------->0,5y-------->1,5y

Có hệ \(\left\{{}\begin{matrix}24x+27y=0,78\\x+1,5y=\dfrac{2,56}{64}\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,01\\y=0,02\end{matrix}\right.\)

Giả sử \(CuSO_4\) phản ứng hết, dung dịch C có: \(\left\{{}\begin{matrix}n_{MgSO_4}=x=0,01\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=0,5y=0,5.0,02=0,01\left(mol\right)\end{matrix}\right.\)

\(MgSO_4+BaCl_2\rightarrow MgCl_2+BaSO_4\) (1)

0,01-------------------------------->0,01

\(Al_2\left(SO_4\right)_3+3BaCl_2\rightarrow3BaSO_4+2AlCl_3\) (2)

0,01------------------------>0,03

Từ PTHH (1), (2) có: \(\Sigma n_{BaSO_4}=0,01+0,03=0,04\left(mol\right)< 0,05\left(mol\right)_{theo.đề}\)

=> Giả sử sai, \(CuSO_4\) dư 

\(CuSO_4+BaCl_2\rightarrow BaSO_4+CuCl_2\)

0,01<-----------------0,01

\(CM_{CuSO_4}=a=\dfrac{x+1,5y+0,01}{0,2}=\dfrac{0,01+1,5.0,02+0,01}{0,2}=0,25\left(M\right)\)

Trong A:

\(n_{Al}=0,02\left(mol\right)\\ n_{Mg}=0,01\left(mol\right)\)

a, PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)

\(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_{2\downarrow}\)

\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)

b, Ta có: \(n_{Mg}=\dfrac{9,6}{24}=0,4\left(mol\right)\)

Theo PT: \(n_{HCl}=2n_{Mg}=0,8\left(mol\right)\)

\(\Rightarrow C_{M_{HCl}}=\dfrac{0,8}{0,2}=4\left(M\right)\)

c, Theo PT: \(n_{MgO}=n_{Mg}=0,4\left(mol\right)\)

\(\Rightarrow m_{MgO}=0,4.40=16\left(g\right)\)